iRASPA Community

iRASPA => General => Topic started by: Z.GAO on March 17, 2023, 09:03:21 AM

Title: Why are absolute/excess sorptions calculated consistently?
Post by: Z.GAO on March 17, 2023, 09:03:21 AM

Dear Prof. Dubbeldam and RASPA community,
When calculating the adsorption of propylene in MOF, I set the porosity in the input file. However, why are the values for absolute and excess adsorption still the same when helium porosity is set?
Below is my input file.

Best Regards!
Z.Gao
Title: Re: Why are absolute/excess sorptions calculated consistently?
Post by: David Dubbeldam on June 13, 2023, 12:59:20 PM
The values are not the same. Excess is slightly smaller.

In the limit of low pressure, excess and absolute adsorption become equal. They start to deviate at high pressures.